ammonia. therefore, the pressure in the system drops. by increasing the reactor pressure, more ammonia is formed as the system responds by reducing the pressure. this reactor, then, is run at a very high pressure-- over 2,000 pounds per square inch. the gas mixture is passed quickly over the catalyst, withdrawn, and the ammonia removed by cooling. removal of the ammonia also favors its formation. here again is the ammonia synthesis reaction. if we remove some of the ammonia, the equilibrium shifts to the right as more nitrogen and hydrogen react to moderate that loss. after the ammonia is removed, the unreacted nitrogen and hydrogen are recycled through the reactor. it is extraordinary that overall, about 99% of the reactants are converted to ammonia, a very efficient process, thanks to le chatelier's principle. to review... chemical reactions occur as a result of molecular collisions. all chemical reactions have an activation energy. in order to react, colliding molecules must have enough kin

[barking] first we started smelling ammonia and then we came across this. 3. hotch: how many bodies? seaver: that shallow grave was empty. rossi: you think our victim was in it? it looked fresh. so he probably took her down to be buried. and that's when she escaped. forensics thinks some of these graves may be up to 10 years old. man: got another one! what the hell? jeez. garcia needs to check missing persons cases going back at least 10 years. garcia said 8 teenage girls have gone missing from the carolinas in the past decade. the hospitalized jane doe was blond. 3 of the 8 are blondes. what about the recent missing person reports? nothing came up. i'm going to put you on speaker, garcia. so, your girl wonder just got a call from raleigh p.d. who heard we were looking for for a missing person. it turns out that shreveport police found an abandoned car today that is registered to a mr. and mrs. linda and don owens of raleigh, north carolina. what's that got to do with this? ok, this is why this is important. it turns out mr. and mrs. owens let their daughter,

and freon have been the two main ways to keep big things cool ammonia refrigerants have always been valued for the relatively low cost as well as better cooling stats that's been balanced against their overpowering smell and serious toxicity freon on the other hand and lower toxicity levels and is totally odorless which actually may make freon leaks more difficult to spot it's uses waned in recent decades as it's destroying qualities have become better known a major reason both then cooper and so she opted against it. freon doesn't have. any kind of smell. it's going to have a gas and in case of major leaks it settles down to the ground. presence there so if they enter a room with a freon leak they can experience oxygen deficiency which may result in always on thing or even death when you know them. so while the sun keep track does it use the silently dangerous freon the gallons of ammonia pumping throughout. the company responsible for producing the first. in case of a leak they have three levels of warning depending on the concentration of whole sections of the piping can be close

they are still not sure but ammonia has been ruled out. >> penalties handed down to st. mary's men's basketball deem tour recruiting violations will stand. the stool learned appeal failed as a result head coach randy been net will serve a five-game suspension and not able to recruit off season. >>> two of the nhl's undefeated teams will square off. the sharks tomas hertl is expected to play. despite leaving saturday's game with an injury. he was named the first star. tonight's zbam on the nbc sports network. >> true hockey sensation talking about that guy. >> ninja hertl. >> inside look at the rock. the former alcatraz prisoner talking to tourists. >>> live to southern california give you a live look at l.a.x., police are investigating the second dry ice explosion at this airport. the second one happening last night. this is found below an airplane at a gate. they are looking for the person responsible. nobody was hurt. >> 5:23 now. today is california's first ever pacific leather-backed turtle conservation day. they are on both the state and federal lists of threatened

. >> the solid rocket motors of the shuttles that take off are filled with ammonia perchlorate. >> pepcon employees run for their lives. >> the employees know what is happening and they all took off. they self-evacuated across the desert. >> before firefighters arrive, there's a massive explosion. >> oh! >> that's going to be loud. >> i saw the explosion about five or six seconds before we actually heard it. up to this point, that was the biggest explosion i had ever seen. >> firefighters are stopped in their tracks by the blast and back off. >> the fire chief was driving and got the window blown out. both groups of people were slightly injured. >> we could see the shockwave coming across the desert and we just ducked down, tried to get under the dash. but it was too low. the windshield came out and caught me in the forehead. >> others ten miles away in las vegas hear and feel the shockwave. >> we honestly thought that there had been an airplane crash or something like that. >> but the biggest blast is yet to come. several additional fire departments respond. >> we were en route to the di

some of this is in the form of ammonia gas which is bubbled into the irrigation water and reaches the fields during irrigation events. but a large amount -- about 75% -- is applied in dry form one month before they actually plant the seeds. matson: they were worried that if they didn't get it on early they might not be able to get it on later when it starts raining or if it starts raining. so they were trying to avoid risk. of course, what they didn't realize is that they were probably losing a lot of nitrogen before they ever even got the seeds into the ground. narrator: and this excess nitrogen can be damaging to the environment. matson: one of the problems with all that extra nitrogen going onto land and fertilizer is that it doesn't all get used by plants. it doesn't all get taken up. in fact, maybe on average 50% of it doesn't stay in agriculture systems but rather gets transported out of the fields where they were applied, and the trog goes off to the atmosphere in a number of different forms including nitrous oxide, which is a greenhouse gas, nitric oxide which is an air pollut

will it's crazy the stuff that they were putting in because methane from elder hide ammonia arsenic kerosene acetone let's paint thinner believable let's move on to. the experiment on poor black citizens of the united states they were calling them simpletons at the time they were picking an edge with poor black citizens at the time it was basically infecting them with syphilis that's exactly they were doing this was going on between one nine hundred thirty to one thousand nine hundred seventy two they were infected upwards of four hundred individuals many of them women twenty eight people died directly from the disease several children were born with with right the disease of course and it was horrible what they were doing to them they were telling these to these people that you know were looking into with this mysterious new disease many of them didn't even know what was going on they were told that they were being administered in an a job but really they were just given aspirin and they were conducting all sorts of experiments to find out how syphilis affects the black population really re

some of this is in the form of ammonia gas, which is bubbled into the irrigation water and reaches thelosing a lot of nitrogen before they ever even got the seeds into the ground. narrator: and this excess nitrogen can be damaging to the environment. matson: one of the problems with all that extra nitrogen going onto land and fertilizer is that it doesn't all get used by plants. it doesn't all get taken up. in fact, maybe on average 50% of it doesn't stay in agriculture systems but rather gets transported out of the fields where they were applied, and the nitrog goes off to the atmosphere in a number of different forms, including nitrous oxide, which is a greenhouse gas, nitric oxide, which is an air pollutant. and some of the nitrogen in agriculture fields just leeches out through the soils into groundwater systems, or it runs off the surface into surface-water systems, like streams and rivers and lakes. and there it causes a number of different problems. the big issue for us is how to manage nitrogen, that nitrogen fertilizer, better so that we can still increase plant growth, we can

so i decided to make something ammonia rich with lots of nutmeg and leave it a while and see what happensof the things we are doing, they are pure experimentation for experimentation sake and it's pretty damn delicious. >> i like that. >> it's another food item on your shelf. me as a cook, that's what i want. these are two years old cherries with the cherry pits. and wild roses. five years old wild roses. very deep, intense. >> this is amazing. >> they're not just thinking about what tastes good now but they're talking about will it taste good in two years if you ferment it or age it or dry it. >> we like to ferment it. we add bacteria to it, so in three years time, it becomes utter delicious. the diversity, you're looking at fermentations and different bacteria, looking at different molds, yeast, all sorts. it's absolutely enormous. >> there is stuff rotting in jars and vats that these experiments in fermentation and flavor. what they are all doing some sinister -- down there, i know. >> this is the ferment from wild spinach which grows around here. no one uses them. reminiscent of foie

our first ammonia-free permanent color, poweil.red by o olia propels color deep.us, vivid color. visibly improves and restores hair. olia by garnier. a cuas bargain bleach. gives you twice as many loads that's twice as many white shirts! that's twice as many white socks! and twice as many white gloves! clorox. one cup. twice as many loads. there should be some way to make it easier. [ doorbell rings ] what is a wetjet? some kind of a mopping device. morty, there's a lot of dirt on here. it's almost like dancing. [ both humming ] the swiffer dance. [knock] no one was at home, but on the kitchen table sat three insurance policies. the first had lots of coverage. the second, only a little. but the third was... just right! bear: hi! yeah, we love visitors. that's why we moved to a secluded house in the middle of the wilderness. just the right coverage at just the right price. coverage checker from progressive. >>> taking a look at your headlines, it was a bumpy first day for americans looking to sign up for health insurance. they were met with era messages or long wai

officers stayed on scene at the intersection of shoor cot and zenker rod to investigate reports of ammonia all clear. this morning they weren't sure what doesed that spell. >> a new plan in fremont is raising concerns about financial profiling. the city could decide to set up surveillance cameras in several neighborhoods not based on crime but on income information from the census. live at central park, near police headquarters. good morning. >> good morning, marla. this is in response to a recent increase in home burglaries here. what the police department is asking the council to do is approve slant crams but what's different about this plan is that the cameras will go up in low to moderate income neighborhoods, based on u.s. census data. here are some of those neighborhoods. ardenwood, central downtown, south donedale neighborhood and the files district. police say it's not the intend to focus on one type of less dent. it's part of a larger plan to put these up around the entire city. some residents are voicing concern flas the cameras have a feeling of big brother watching and could fe

the the mercury news reports the ammonia like smell is likely to be jet fuel.that's because the direction of the wind usually changes this time of year causing aircraft exhaust to be noticeable when driving on highway 101. airport officials say short- term exposure to the smell should not cause any health problems. >>> all right our time now 6:57. coming up for you on mornings on 2. we have developing news, police investigating the suspicious death of a baby taken to san fransisco general hospital a lot of questions around this tragedy. >> possible good news in the b.a.r.t. labor talks, what the union decided not to do that could be an indication of a deal in the works. stay with us. we'll be right back. with crescent dogs. just separate, add hot dogs, cheese, roll 'em up, and bake. lookin' hot, c-dog. pillsbury crescents. make dinner pop. but press them flat, add sauce... and some pepperoni and cheese... and school nights turn into grands mini pizza nights. pillsbury grands biscuits. make dinner pop! >> reporter: san francisco police investigating the suspicio

the san jose mercury news reports the ammonia like smell is probably jet fuel. the direction of the winds usually changes this time of year causing plane exhaust to be noticeable when you drive on highway 101. short-term exposure to that smell probably won't cause any health problems. >>> time now is 5:11. we have new information about that pg&e gas line that's been a source of concern in san carlos. the similarities between the construction of that pipeline and the one that exploded in san bruno. >> also targeting an ongoing problem with trash. the reason san fransisco police are planning to keep a really close eye on those recycling bins. >> good morning right now we're looking pretty good when it comes to driving. this is a look at the golden gate bridge and traffic is light. >> clear skies out there, a little chill for some, not too bad for others. it will be sunny today and cooler. we'll have the forecasted highs and talk about a system due tomorrow. i want you to know stuff i want you to be kind. i want you to be smart. super smart. i want one thing in a d

they will supply mosaic with a million tons of ammonia used in makes fos cate fates and facebook fallinglow $50 a share, although back up just a bit, ahead of its earnings call on wednesday. all things d reporting that facebook has decided not to launch video adds this year. it's trading at 50.63. to the bond market, rick santelli, who has been tracking the action out at the cme. hi, rick. >> hi, tyler. if one of the fed's secret goals was to take volatility out of every market except for going up in stocks, mission accomplished. look at it, we have two-year note auction today. wasn't a bad auction. two-day chart, two-year note yields within a three quarters of basis point range. go to the longest end of the curve where the volatility is, 30-year bond, two-day chart, three basis point range low to high. look overseas, look at the boom. three basis point range over the last two days. dollar index, .3 of a cent range. want to see what's going on think quantitative easing and other issues. year-to-date chart small range but at the bottom all the way back towards february. back to you. >> ri

the overwhelming smell of ammonia from cat urine combined with pet hair makes breathing difficult. unlike other areas, the air in jessica's room is much cleaner. >> it doesn't hurt to breathe in this room. your eyes don't burn. your nostrils don't burn, your throat doesn't suddenly hurt. you don't feel like someone's sitting on your chest. >> with the house in such disorder, jessica finds day-to-day life mentally draining and physically exhausting. >> it takes ten times more work and effort to do simple things than it should take. to take a shower, you have to get all your stuff from your bedroom, make sure you have your flip flops on, step over your baby gate, walk to the other end of the house. i don't walk around barefoot. i don't want stuff on my feet. it just flat-out grosses me out. to cook anything, i have to go to my fridge in my room, get everything i needed, get all my utensils and bring it into the kitchen to prepare my food, then clean it and take it all back to my room. to sweep and mop, i have to do a quarter to a third of a room at a time. i have to move everything a

the ammonia-like smell is likely jet fuel, it's reported.hange direction causing aircraft exhaust to be noticeable when driving on highway 101. airport officials say short- term exposure to the smell should not cause any health problems. >>> a stanford university student accused of driving drunk and causing a deadly crash on saturday is still in the hospital. the chp says he will be booked as soon as he's released. investigators say 24-year-old zachary katz drove the wrong way on highway 101 in south san francisco and hit a taxicab head-on. 62-year-old pay dry juan soldelvia of puerto rico died in the cash. he was in the cab on his way to sfo. a second passenger and the cabdriver were also hurt. >>> new this morning, the nobel prize for physics was apardonned hours ago to francois englert and peter higgs. both made discovery on why matter has mass. that led to last year's amazing discovery of the higgs particle, also known as the god particle which are some are calling the greatest scientific discovery in decades. >>> 8:27. one win away. tal

they will fly mosaics with 1 million tons of ammonia used to make the phosphates. over to you. >>> a tough, very difficult transition to understand. consul energy selling five of the key coal mines. shares trading lower. first on cnbc is brad harvey, chairman and ceo of consul energy. welcome to squawk on the streets, sir. good to see you. >> good to be here. you are only getting out of thermal. you still want to be able to be in that expert call, because i would think that -- you want to get out of coal entirely and go all in nat gas. >> the fastest growing fuel internationally is coal. the fastest growing fuel inside the united states is natural gas. it is a natural for us to hit both markets. this is just a move to get away from the nongrowth domestic side and grow worldwide sbeas well a domestically. >> is this all a statement that the epa has said you are not going to build any more coal plants in this country and why not diversify away given this country has turned very hard against using coal as a fuel. >> well, yeah. we -- this administration says we should

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our first ammonia-free permanent color, poweil.red by o olia propels color deep.[ doorbell rings ] let's see what's cookin'. look at this. that's a swiffer. i don't have to climb up. did you notice how clean it looks? morty are you listening? morty? [ morty ] i'm listening! i want you to know. morty are you listening? morty? ♪ don't disguise bad odors in your trash. morty are you listening? morty? neutralize them and freshen. with glad odorshield with febreze. did nana ever give you cheerios when you were a little kid? yeah, she did. were cheerios the same back then? cheerios has pretty much been the same forever. so...when we have cheerios, it's kind of like we are having breakfast with nana... yeah... ♪ yeah. you're so smart. yeah. it's holiday time, and no fruit is as versatile as our ocean spray cranberries, which is why were declaring it the unofficial official fruit of the holidays! the fig's gonna be so bummed. [ laughs ] for holiday tips and recipes, go to oceanspray.com. l'oreal introduces newfect. voluminous butterfly mascara. l'oreal's revolutionary asy