. >> reporter: barbara sloan and a former sheriff's deputy claim they were falsely accused of arson.il for 16 months? >> it ruined my life. >> reporter: the findings of an arson investigator was hired by the defense. >> i think there are other cases, other innocent victims out there. >> reporter: nearly five years ago abc news was given access to this elite unit, an inside look at what made them the best in the nation. >> sadie is an accelerant detection canine. she's a food reward dog. >> reporter: the unit is run by a charismatic and confident former police detective, jack valentine, who by his own admission had no prior background in fire investigations. under his leadership, the unit's clearance rate skyrocketed from solving 22% of the cases in 2007 to 65% in 2010, the highest in the country. back then the team was proud to boast about their success. not now. >> can we talk to you about the investigation? i take it the answer is no. >> reporter: back when they were talking to us, the captain made an interesting statement about their investigative techniques. >> we used to think t